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Shunsui Kyōraku (京楽 春水, Kyōraku Shunsui) is the Captain of the 8th Division in the Gotei 13. His lieutenant is Nanao Ise.

Kyōraku is a laid back and flamboyant man, evident in his style of dress and general attitude, and he is rarely seen without a smile on his lips. In his off time, he can be seen drinking sake in bars and napping. He likes steamed buns that go with sake, but dislikes powdered green tea. Other times, he likes to chase after women, particularly his lieutenant, Nanao Ise, whom he calls "my Nanao-chan" (Lil' Nanao in the English Dub). Nanao will often respond by hitting him with whatever she has on hand. He would have also done this when Lisa Yadōmaru was his lieutenant, which shows that teasing is a part of his personality. Kyōraku tends to use a more familiar speech style than most other characters. He generally refers to his fellow captains and Shinigami by their first name followed by an honorific. Kyōraku is a peace-loving man who will always try to talk his way out of a fight, though he doesn't wish to insult opponents by refusing to fight. The slightly eccentric Kyōraku also seems to like making an impression on opponents. He also dislikes taking the life of innocent people, as he left Chad alive when Nanao offered to kill him.

Captain Kyōraku also wrote a romance novel titled "Rose-colored Path", which ran in Seireitei Communication, but was very unpopular. His photo collection, on the other hand, titled "Using Arms as My Pillow", became widely popular, and was quickly sold out, partially because it came out in lesser number of copies than similar collections by the other captains. Kyōraku also doesn't seem to care that his autobiography, "My Kittens Are So Shy," is the absolute worst-selling book.

Though Kyōraku tries to talk his way out of a fight, he does insist on fighting when the situation is grave, as seen in his battle with the First Espada, Coyote Starrk. When Starrk asked that they only pretend to fight, he replied that he couldn't do that "this time", as much as he prefers to do things the same way. He is also one of the most proficient combatants in Soul Society, and maintains a level of honor and integrity when engaging in battle, much like his best friend Jūshirō. He refuses to fight with children or even in the presence of a child. He always maintains a semblance of respect for his opponent and is polite in combat situations and prefers to fight one on one.Even when fighting powerful opponents, like Starrk or Aizen, he never (or at least rarely) loses his cool, going as far as to make small talk and joke around with his opponents.

Despite being one of the strongest and oldest captains, Kyōraku retains a level of humbleness and isn't overly arrogant about his strength, although when fighting Starrk, he does comment on how the fight "wouldn't be too easy" even after finding out that Starrk is the 1st Espada, but he does recognize that Hitsugaya has the potential to become stronger than him given enough time. Kyōraku has shown a great distaste for fighting, telling Love Aikawa that it doesn't matter whether you owe someone or they owe you, as soon as you start fighting, you are in the wrong either way.